Journal of the Chemical Society (Resumed)

768. Studies with acetylenes. Part II. Some reactions of Grignard reagents with propargylic halides. Model linoleic and linolenic acid systems

SS Nigam, BCL Weedon

Index: Nigam; Weedon Journal of the Chemical Society, 1957 , p. 3868,3872

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Citation Number: 4

Abstract

Copper-catalysed condensations of hex-l-ynylmagnesium bromide with l-bromohept-2-yne and 1: 4-dichlorobut-2-yne give mainly trideca-5: 8-diyne and hexadeca-5: 8: 1 l-triyne, respectively. These hydrocarbons are converted by partial catalytic hydrogenation into the

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