The Journal of Organic Chemistry

Synthesis and chemistry of ethynylsulfur pentafluoride

FW Hoover, DD Coffman

Index: Hoover,F.W.; Coffman,D.D. Journal of Organic Chemistry, 1964 , vol. 29, p. 3567 - 3570

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Citation Number: 58

Abstract

2-Chlorovinylsulfur pentafluoride, first synthesized'J photocatalytically, was prepared in this study by thermal addition of SF5Cl to a~ etylene.~ The other SF5 compounds in the four-step sequence are new and have been identified by elemental and spectral analyses. H'nmr spectroscopy has served to elucidate the cis and trans configurations of these and other SFB- substituted ethylenes obtained in this study (see Table I). The spectra of the cis and trans ...