Hydrolysis of t-Alkyl Trifluoroacetates
A Moffat, H Hunt
Index: Moffat; Hunt Journal of the American Chemical Society, 1958 , vol. 80, p. 2985
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Citation Number: 4
Abstract
According to Hine, 2" in order for this cleavage to occur without acid catalysis, the carbonium ion to be formed should be more stable or the anion to be formed should be less basic or both." Several examples of this type of uncatalyzed cleavage are known which involve the formation of a more stable carbonium ion (triphenylmethylcarbonium ion, for example). 3
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