Chemical Communications

Pd-catalyzed synthesis of symmetrical and unsymmetrical siloxanes

Y Kurihara, Y Yamanoi, H Nishihara

Index: Kurihara, Yu; Yamanoi, Yoshinori; Nishihara, Hiroshi Chemical Communications, 2013 , vol. 49, # 96 p. 11275 - 11277

Full Text: HTML

Citation Number: 8

Abstract

A palladium-catalyzed arylation of hydrosiloxanes was developed for the synthesis of symmetrical and unsymmetrical siloxanes. Reactive functional moieties such as hydroxy or cyano groups were able to tolerate the reaction conditions and several novel unsymmetrical siloxanes were synthesized in moderate to high yield.

Related Articles:

Catalytic synthesis of silyl formates with 1atm of CO 2 and their utilization for synthesis of formyl compounds and formic acid

[Itagaki, Shintaro; Yamaguchi, Kazuya; Mizuno, Noritaka Journal of Molecular Catalysis A: Chemical, 2013 , vol. 366, p. 347 - 352]

Supported gold nanoparticle catalyst for the selective oxidation of silanes to silanols in water

[Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Chemical Communications, 2009 , # 35 p. 5302 - 5304]

Photooxygenation of Aryldisilanes via Photoinduced Electron Transfer

[Mizuno, Kazuhiko; Tamai, Toshiyuki; Hashida, Isao; Otsuji, Yoshio Journal of Organic Chemistry, 1995 , vol. 60, # 9 p. 2935 - 2937]

Structures of tetrasilylmethane derivatives (XMe2Si) 2C (SiMe3) 2 (X= H, Cl, Br) in the gas phase, and their dynamic structures in solution

[Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D. Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42]

Structures of tetrasilylmethane derivatives (XMe2Si) 2C (SiMe3) 2 (X= H, Cl, Br) in the gas phase, and their dynamic structures in solution

[Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D. Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42]

More Articles...