Synthesis of 1-oxadecalins from anisole promoted by tungsten

EC Lis Jr, RJ Salomon, M Sabat…

Index: Goosen, Andre; Marais, Charles F.; McCleland, Cedric W.; Rinaldi, Fabrizio C. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1995 , # 6 p. 1227 - 1236

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Citation Number: 10

Abstract

... Journal of the American Chemical Society. ... This type of “η 2 -allyl” character has been previously documented for both Mo and W nitrosyl systems.(11-13). Stirring the allyl complex 18 with a nucleophile (NaBH 4 or NaCN) at 0 °C affords the addition products 19 and 20 ...