ω-Hydroxy-1-alkanesulfonyl chlorides

JF King, MR Webster, N Chiba, JK Allen…

Index: King, J. F.; Webster, Michael R.; Chiba, Naoki; Allen, Julie K.; Parker, Kenneth J. M.; et al. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 31, p. 161 - 176

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Citation Number: 6

Abstract

Abstract The general synthesis of hydroxyalkanesulfonyl chlorides is illustrated by the preparation of 6-hydroxy-1-butanesulfonyl chloride (2e) and 5-hydroxy-1-pentanesulfonyl chloride (2d) as fairly stable, oily liquids (of∼ 95% purity) characterized by 1Hmr, 13Cmr and infrared spectra, and by conversion both to the corresponding sultones (3) and to crystalline acetoxy-piperidides (6); 2d and 2e form apparent polymers, very slowly on ...