Ambident Reactivity of Chloro (dialkylamino)(diphenylphosphinoyl) methanes

VP Morgalyuk, TV Strelkova, EE Nifant'ev

Index: Morgalyuk, Vasilii Petrovich; Strelkova, Tat'Yana Vladimirovna; Nifant'Ev, Eduard Eugenievich Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 1 p. 93 - 100

Full Text: HTML

Citation Number: 5

Abstract

The chemical properties of chloro (dialkylamino)(diphenylphosphinoyl) methanes have been studied using the simplest compound of this series, chloro (dimethylamino)( diphenylphosphinoyl) methane, as an example. Chloro (dimethylamino)( diphenylphosphinoyl) methane shows ambident reactivity when reacting with electrophiles and nucleophiles depending on coreactant nature, it behaves as either electrophilic ...

Related Articles:

Sodium in liquid ammonia—a versatile tool in modifications of arylphosphine oxides

[Stankevic, Marek; Wlodarczyk, Adam; Jaklinska, Magdalena; Parcheta, Renata; Pietrusiewicz, K. Michal Tetrahedron, 2011 , vol. 67, # 45 p. 8671 - 8678]

… the reactivity of 2-amino-3-chloro-and 2, 3-dichloroquinoxalines towards Ph 2 PH and Ph 2 PLi and of the properties of diphenylphosphanyl-quinoxaline P, N and P, P …

[Adam, Mohamed Shaker S.; Mohamad, Ahmad Desoky; Jones, Peter G.; Kindermann, Markus K.; Heinicke, Joachim W. Polyhedron, 2013 , vol. 50, # 1 p. 101 - 111]

Spin-trapping properties of 5-(Diphenylphosphinoyl)-5-methyl-4, 5-dihydro-3H-pyrrole N-Oxide (DPPMDPO)

[Nishizawa, Masahiro; Shioji, Kosei; Kurauchi, Yoshimitsu; Okuma, Kentaro; Kohno, Masahiro Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 3 p. 495 - 497]

… the reactivity of 2-amino-3-chloro-and 2, 3-dichloroquinoxalines towards Ph 2 PH and Ph 2 PLi and of the properties of diphenylphosphanyl-quinoxaline P, N and P, P …

[Adam, Mohamed Shaker S.; Mohamad, Ahmad Desoky; Jones, Peter G.; Kindermann, Markus K.; Heinicke, Joachim W. Polyhedron, 2013 , vol. 50, # 1 p. 101 - 111]

Stereospecific nucleophilic substitution of optically pure H-phosphinates: a general way for the preparation of chiral P-stereogenic phosphine oxides

[Xu, Qing; Zhao, Chang-Qiu; Han, Li-Biao Journal of the American Chemical Society, 2008 , vol. 130, # 38 p. 12648 - 12655]

More Articles...