Reactions of Esters with Tertiary Amines. I. Benzyl Esters from Methyl Esters and Benzyldimethylamine1
EL Eliel, RP Anderson
Index: Eliel; Anderson Journal of the American Chemical Society, 1952 , vol. 74, p. 547
Full Text: HTML
Citation Number: 26
Abstract
The recent finding2 that benzyldimethylamine will alkylate methyl cyanoacetate and tricarbethoxymethane prompted an investigation of the reaction of this amine with the methyl esters of acids which are not readily decarboxylated. It was found that when a mixture of the methyl ester of such an acid and benzyldimethylamine is heated to a temperature close to 200'in an atmosphere of nitrogen, a gentle but steady evolution of trimethylamine occurs, ...
Related Articles:
NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides
[Li, Yi; Du, Wenting; Deng, Wei-Ping Tetrahedron, 2012 , vol. 68, # 18 p. 3611 - 3615]
[Bahrami, Kiumars; Khodaei, Mohammad M.; Targhan, Homa; Sheikh Arabi, Mehdi Tetrahedron Letters, 2013 , vol. 54, # 37 p. 5064 - 5068]
A De Novo Asymmetric Approach to 8a-epi-Swainsonine
[Coral, Jason A.; Guo, Haibing; Shan, Mingde; O'Doherty, George A. Heterocycles, 2009 , vol. 79, # C p. 521 - 529]
[Hu, Bin; Li, Yunfeng; Li, Zhongjun; Meng, Xiangbao Organic and Biomolecular Chemistry, 2013 , vol. 11, # 25 p. 4138 - 4141]
[Barry, J.; Bram, G.; Decodts, G.; Loupy, A.; Orange, C.; et al. Synthesis, 1985 , # 1 p. 40 - 45]