Introduction of the amide function into 1, 3, 2-dioxaphospholenes with pentavalent phosphorus

F Ramirez, J Bauer, CD Telefus

Index: Ramirez,F. et al. Journal of the American Chemical Society, 1970 , vol. 92, p. 6935 - 6942

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Citation Number: 12

Abstract

Abstract: Carbamyl-l, 3, 2-dioxaphospholenes with pentavalent phosphorus were synthesized from a-ketoaldehydes, iswyanates, and trialkyl phosphites. The phospholenes were converted into phosphate esters of 0-keto-ahydroxyamides. These underwent very rapid hydrolyses to 0-keto-a-hydroxyamides. he 2, 2, 2-trialkoxy-1, 3, 2-dioxaphospholenes (1) are

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