The Journal of organic chemistry

Total synthesis of dysiherbaine

D Phillips, AR Chamberlin

Index: Kappes, Dag; Gerlach, Hans Synthetic Communications, 1990 , vol. 20, # 4 p. 581 - 587

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Citation Number: 37

Abstract

... Volume: Page: ... be obtained via an alkylation of a protected glutamate (4) with a glycosyl electrophile (5). This overall synthetic strategy is ... to the pyroglutamate 19 (Scheme 3, pathway 2). Enolization of 19 would then give the corresponding enolate 20, a species ...