CuI-catalyzed hydroxylation of aryl bromides under the assistance of 5-bromo-2-(1H-imidazol-2-yl) pyridine and related ligands
J Jia, C Jiang, X Zhang, Y Jiang, D Ma
Index: Jia, Jianhuan; Jiang, Chenglin; Zhang, Xiaojing; Jiang, Yongwen; Ma, Dawei Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5593 - 5595
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Citation Number: 16
Abstract
A number of substituted 2-pyridin-2-yl-1H-benzoimidazoles and 2-(1H-imidazol-2-yl) pyridines were screened for promoting CuI-catalyzed hydroxylation of aryl bromides, which led to the discovery of the combination of CuI and 5-bromo-2-(1H-imidazol-2-yl) pyridine as an effective catalytic system for this transformation. Both electron-rich and electronic- deficient aryl bromides could be converted into the corresponding substituted phenols in ...
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