Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts
BJ Truscott, AMZ Slawin, SP Nolan
Index: Dalton Transactions, , vol. 42, # 1 p. 270 - 276
Full Text: HTML
Citation Number: 20
Abstract
... Dalton Trans., 2013, 42, 270-276 Show Compounds Show Chemical Terms. ... In the conjugate addition study, 13 steric variations between three NHC ligands (IPr (2a), ICy (2b) and IDD (2c), Scheme 1) were found to be responsible for observed differences in catalytic activity. ...
Related Articles:
Convenient synthesis of alkoxyhalosilanes from hydrosilanes
[Journal of Organometallic Chemistry, , vol. 689, # 20 p. 3258 - 3264]
[Journal of the American Chemical Society, , vol. 113, # 26 p. 9887 - 9888]
Hydrosilylation Catalyzed with Rh (PPh3) 3Cl/Ionic-Liquid–Functionalized SiO2
[Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 185, # 2 p. 484 - 490]
Effect of triarylphosphane ligands on the rhodium??catalyzed hydrosilylation of alkene
[Applied Organometallic Chemistry, , vol. 28, # 2 p. 120 - 126]
[Journal of Organometallic Chemistry, , vol. 253, # 3 p. 349 - 362]