The products of substitution and cyclization in the reaction of (2-bromoethyl)(3-chloropropyl) dimethylsilane with triflamide

EN Suslova, AI Albanov, BA Shainyan

Index: Suslova; Albanov; Shainyan Russian Journal of General Chemistry, 2013 , vol. 83, # 3 p. 453 - 461 Zh. Obshch. Khim., 2013 , vol. 83, # 3 p. 399 - 407,9

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Abstract

Abstract In order to synthesize the first seven-membered N-triflylazasilacycloalkane the reaction of triflamide with (2-bromoethyl)(3-chloropropyl) dimethylsilane was studied. Depending on the reaction conditions bis (3-chloropropyl) tetramethyldisiloxane, 3- trifluoromethylsulfonylaminopropyl (3-chloropropyl)-tetramethyldisiloxane,(2- triflamidoethyl)(3-chloropropyl) dimethylsilane, bis (3-triflamidopropyl) ...