Organometallics

Heterobimetallic Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous Syngas Conversion

NM West, JA Labinger, JE Bercaw

Index: Field, John S.; Haines, Raymond J.; Parry, Campbell J.; Sookraj, Sadesh H. South African Journal of Chemistry, 1993 , vol. 46, # 3/4 p. 70 - 74

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Citation Number: 22

Abstract

... Figure 2. X-ray structure of 8-Me. ... the rate constant of migratory insertion for Re(CO) 5 Et in CH 3 CN (the only reported value) is 3.8 × 10 –5 s –1 at ... migratory insertion in the presence of ZnCl 2 (THF); the product exhibits two 1 H NMR signals (4.20 and 3.71 ppm, 2 J HH = 14.6 ...