Vinyl cation. Solvolysis of 1-cyclopropyl-1-chloroethylene
M Hanack, T Baessler
Index: Hanack,M.; Baessler,T. Journal of the American Chemical Society, 1969 , vol. 91, p. 2117 - 2118
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Citation Number: 17
Abstract
It is, of course, possible that the accelerated rate of solvolysis of 5 is the result of complex formation between 5 and silver ion, and we are now studying this possibility. The complete absence of any observable reaction between Ag+ and 2-chloro-3, 3-dimethy1-1-butene, however, is evidence against a specific silver ion catalysis. We therefore interpret the foregoing observations, at present, in terms of the formation of an intermediate vinyl cation ...
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