Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions
…, H Meng, L Jin, F Mo, Y Zhang, J Wang
Index: Qiu, Di; Jin, Liang; Zheng, Zhitong; Meng, He; Mo, Fanyang; Wang, Xi; Zhang, Yan; Wang, Jianbo Journal of Organic Chemistry, 2013 , vol. 78, # 5 p. 1923 - 1933
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Citation Number: 14
Abstract
A synthetic method based on Sandmeyer-type reactions to access both tin-and boron- substituted arenes from nitroaniline derivatives is described. This transformation can be applied to the synthesis of a series of functionalized trimethylstannyl arylboronates. In addition, the chemoselective reaction of the Stille and Suzuki–Miyaura cross-coupling reactions is explored, and a series of m-and p-terphenyl derivatives have been ...
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