Journal of Organometallic Chemistry

Chloraminosilanes II. Preparation and spectroscopic studies on alkyl-(dimethylamino) chlorosilanes

SS Washburne, WR Peterson

Index: Washburne,S.S.; Peterson,W.R. Journal of Organometallic Chemistry, 1970 , vol. 21, p. 59 - 64

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Citation Number: 33

Abstract

Abstract Several new compounds containing both chloro and dimethylamino groups linked to silicon have been prepared. The general method involved reacting a solution of the appropriate polychlorosilane in ether at ca.-50 with a chilled ethereal solution of dimethylamine. Prepared in this fashion were CH 3 Si (NMe 2) Cl 2, CH 3 Si (NMe 2) 2-Cl, PhSi (NMe 2) Cl 2, PhSi (NMe 2) 2 Cl, CH 3 (H) Si (NMe 2) Cl,(CH 3) 2 Si (NMe 2) Cl, CH ...