Oxidative decomposition of 1, 1'-azoadamantane by thianthrene cation radical. Carbocationic chemistry from a free radical source
…, PS Engel, AKMM Hoque, DE Keys…
Index: Bae, Dong Hak; Engel, Paul S.; Hoque, A. K. M. Mansurul; Keys, Dalen E.; Lee, Wang-Keun; et al. Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2561 - 2562
Full Text: HTML
Citation Number: 28
Abstract
In the course of studies in the trapping of free radicals, we have discovered that azoalkanes are readily oxidized by aromatic cation radicals in acetonitrile at room temperature. The mechanism of this novel reaction is examined here for the particular case of thianthrenium perchlorate (Th+. C1O4-) and 1, l'-azoadamantane
Related Articles:
Electrocatalytic reduction of alkyl iodides in tetrahydrofuran at silver electrodes
[Paddon, Christopher A.; Bhatti, Farrah L.; Donohoe, Timothy J.; Compton, Richard G. Journal of Physical Organic Chemistry, 2007 , vol. 20, # 2 p. 115 - 121]
Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes
[Khusnutdinov; Schchadneva; Malikov; Dzhemilev Petroleum Chemistry, 2006 , vol. 46, # 3 p. 159 - 163]
[Molle, G.; Bauer, P.; Dubois, J. E. Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4120 - 4128]
The Barbier synthesis: a one-slip Grignard reaction?
[Molle, Gerard; Bauer, Pierre Journal of the American Chemical Society, 1982 , vol. 104, # 12 p. 3481 - 3487]
Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes
[Khusnutdinov; Schchadneva; Malikov; Dzhemilev Petroleum Chemistry, 2006 , vol. 46, # 3 p. 159 - 163]