Substituent Effects of Alkyl Groups on the Decomposition of tert-Alkyl Peroxides

K Matsuyama, T Sugiura…

Index: Matsuyama, Kazuo; Sugiura, Takashi; Minoshima, Yoshihiko Journal of Organic Chemistry, 1995 , vol. 60, # 17 p. 5520 - 5525

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Citation Number: 9

Abstract

In order to clarify substituent effects of alkyl groups on the decomposition of various tert-alkyl peroxides (RCMeZOOR), the decomposition of 1-methoxy-1-(tert-alky1peroxy) cyclohexanes 3 and 1, l-bis (tert-alky1peroxy) cyclohexanes 4 has been studied by use of methods of kinetics and product analysis in cumene with the range of temperatures from 80- 110" C and compared with those of the corresponding peroxyesters (1; R'= CO-t-Bu) and ...