Activation of Weak Organic Bases. VI. The Alkylation of Thiol Esters by Triethyloxonium Salt and Diethoxycarbonium Salt (HC^+(OC2H5) 2, S^-bCl6)

M MORI, M SHIOZAWA, Y BAN…

Index: Mori,M. et al. Chemical and Pharmaceutical Bulletin, 1971 , vol. 19, p. 2033 - 2040

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Abstract

The alkylation of thiol esters with effective alkylating reagents was studied. It was found that the process which afford products was in most cases thermodynamically controlled, which establishes the high susceptibility of the divalent sulfur in thiol esters to the alkylating reagents.