Ga (ClO 4) 3-catalyzed synthesis of quinoxalines by cycloaddition of α-hydroxyketones and o-phenylenediamines
F Pan, TM Chen, JJ Cao, JP Zou, W Zhang
Index: Pan, Fan; Chen, Tang-Ming; Cao, Jia-Jia; Zou, Jian-Ping; Zhang, Wei Tetrahedron Letters, 2012 , vol. 53, # 20 p. 2508 - 2510
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Citation Number: 24
Abstract
A new approach for the synthesis of 2-substituted quinoxalines by Ga (ClO4) 3-catalyzed cycloaddition of α-hydroxyketones and o-phenylenediamines is introduced. The reaction is catalyzed by 10mol% of Ga (ClO4) 3 in EtOH at room temperature. It is performed under simple and mild conditions to afford the product in good yield.
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