Organic sulfur compounds. VIII. Addition of thiols to conjugated diolefins

AA Oswald, K Griesbaum, WA Thaler…

Index: Oswald,A.A. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 3897 - 3904

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Citation Number: 69

Abstract

Addition of ionic and free radical reagents to conjugated dienes usually gives rise to both normal 1, Z-addition and 1, 4-conjugate addition. Kharasch and co-workers reported about a quarter of a century ago 3, 4 that in the presence of peroxides the addition of hydrogen bromide and hydrogen chloride to butadiene resulted predominantly in 1, 4-adducts while in the absence of peroxides mainly the 1, 2-adducts were formed. Carbon tetrachloride and ...

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