The Journal of organic chemistry

Preparative fluorous mixture synthesis of diazonium-functionalized oligo (phenylene vinylene) s

H Jian, JM Tour

Index: Jian, Huahua; Tour, James M. Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3396 - 3424

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Citation Number: 47

Abstract

A series of building blocks for the synthesis of oligo (phenylene vinylene) s (OPVs) and hybrid oligomers were prepared, and alternating Heck coupling and Horner-Wadswoth- Emmons (HWE) reactions were used to couple the building blocks. Model studies were carried out to optimize the reaction strategies. The products were made to bear aryl diazonium functionalities that allow them to be used as surface grafting moieties in hybrid ...