Journal of fluorine chemistry

Some reactions of 1, 2, 3, 4, 7, 7-hexafluorobicyclo [2, 2, 1] hepta-2, 5-diene: Thermolysis and attack by methoxide ion and by bistrifluoromethyl nitroxide

RE Banks, A Prodgers

Index: Banks,R.E.; Prodgers,A. Journal of Fluorine Chemistry, 1984 , vol. 26, p. 169

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Citation Number: 3

Abstract

Abstract 1, 2, 3, 4, 7, 7-Hexafluorobicyclo [2, 2, 1] hepta-2, 5-diene gave 1, 2, 3, 4- tetrafluorebenzene in at least 73% yield when heated to 450 C in a sealed tube; the CF 2 bridge appeared, in part, as octafluorocyclobutane. Nucleophilic attack by sodium methoxide-methanol on the diene occurred exclusively at the CF CF bond, causing the formation of 1, 2, 4, 7, 7-pentafluoro-3-methoxybicyclo-[2, 2, 1] hepta-2, 5-diene and a 1, 4, ...

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Some reactions of 1, 2, 3, 4, 7, 7-hexafluorobicyclo [2, 2, 1] hepta-2, 5-diene: Thermolysis and attack by methoxide ion and by bistrifluoromethyl nitroxide

Abstract

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