Anwendung des trichloracetimidatverfahrens auf 2-desoxy-2-phthalimido-d-glucose-derivative. Synthese von oligosacchariden der “Core-Region” von O- …
G Grundler, RR Schmidt
Index: Grundler, Gerhard; Schmidt, Richard R. Carbohydrate Research, 1984 , vol. 135, p. 203 - 218
Full Text: HTML
Citation Number: 99
Abstract
Abstract N-Phthaloyl derivatives of 2-acetamido-2-deoxy-d-glucose having OH-1 free treated with trichloroacetonitrile and sodium hydride gave the corresponding O-(β-d-glycosyl) trichloroacetimidates which in the presence of diethyl ether· borontrifluoride, led selectively with alcohols to β-d-glycosides. This procedure was applied to the synthesis of oligosaccharides from the core region of mucine-type O-glycoproteins. Thus, β-d-Galp-(1 ...
Related Articles:
Chemical and biochemical aspects of deoxysugars and deoxysugar oligosaccharides
[Zuurmond, H. M.; Klein, P. A. M. van der; Wildt, J. de; Marel, G. A. van der; Boom, J. H. van Journal of Carbohydrate Chemistry, 1994 , vol. 13, # 2 p. 323 - 340]
[Bundle, David R.; Josephson, Staffan Canadian Journal of Chemistry, 1980 , vol. 58, p. 2679 - 2685]
[Carbohydrate Research, , vol. 135, p. 203 - 218]
[Carbohydrate Research, , vol. 135, p. 203 - 218]
[Yakugaku Zasshi, , vol. 77, p. 726,730 Chem.Abstr., , p. 17763]