Regioselective reactions of sulfur, selenium and tellurium chlorides with allyl trimethyl silane

…, NA Makhaeva, LI Larina, SV Amosova

Index: Martynov, Alexander V.; Makhaeva, Natalia A.; Larina, Lyudmila I.; Amosova, Svetlana V. Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 1964 - 1968

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Citation Number: 4

Abstract

Electrophilic addition of SCl2, SeCl2 and SeCl4 to 2 equivalents of allyl trimethyl silane proceeds regioselectively to give bis [2-chloro-3-(trimethylsilyl) propyl] sulfide, selenide and selenium dichloride, respectively. The reaction with TeCl4 affords only diallyl tellurium dichloride. The structures of the compounds were confirmed by 1H, 13C, 77Se and 125Te NMR techniques.