Direct synthesis of diphenyl carbonate by mediated electrocarbonylation of phenol at Pd 2+-supported activated carbon anode
T Murayama, T Hayashi, Y Arai, I Yamanaka
Index: Murayama, Toru; Hayashi, Tomohiko; Arai, Yuji; Yamanaka, Ichiro Electrochimica Acta, 2011 , vol. 56, # 7 p. 2926 - 2933
Full Text: HTML
Citation Number: 10
Abstract
Mediated electrocarbonylation of phenol to diphenyl carbonate (DPC) at a PdCl2-supported activated carbon anode in 1atm CO at 298K was studied. A dry CH2Cl2 or CH3CN solvent and a galvanostatic electrolysis of 1mA were necessary for formation of DPC, while the addition of a base and a supporting electrolyte was also essential. A combination of triethylamine (Et3N) and tetrabutylammonium perchlorate (Bu4NClO4) was suitable in ...
Related Articles:
[Krasutsky, Pavel A.; Kolomitsyn, Igor V.; Krasutsky, Sergiy G.; Kiprof, Paul Organic Letters, 2004 , vol. 6, # 15 p. 2539 - 2542]
[Kandanarachchi, Pramod; Sinnott, Michael L. Journal of the American Chemical Society, 1994 , vol. 116, # 13 p. 5592 - 5600]
[Kandanarachchi, Pramod; Sinnott, Michael L. Journal of the American Chemical Society, 1994 , vol. 116, # 13 p. 5592 - 5600]
[Kandanarachchi, Pramod; Sinnott, Michael L. Journal of the American Chemical Society, 1994 , vol. 116, # 13 p. 5601 - 5606]
Transesterification of dimethyl carbonate with phenol using Brønsted and Lewis acidic ionic liquids
[Deshmukh, Krishna M.; Qureshi, Ziyauddin S.; Dhake, Kishor P.; Bhanage, Bhalchandra M. Catalysis Communications, 2010 , vol. 12, # 3 p. 207 - 211]