Aromatic substitution in the gas phase. Alkylation of arenes by gaseous C4H9+ cations
F Cacace, G Ciranni, P Giacomello
Index: Cacace, Fulvio; Ciranni, Giovanna; Giacomello, Pierluigi Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1513 - 1516
Full Text: HTML
Citation Number: 10
Abstract
Abstract: Butyl cations, obtained in the dilute gas state from the radiolysis of butane in the pressure range from 70 to 750 torr, have been allowed to react with benzene, toluene, and their mixtures or with trace amounts of o-xylene in the gaseous system. The gas-phase butylation yields invariably sec-butylarenes, remarkably free of isomeric byproducts, namely n-and fert-butylarenes. Other alkylation experiments, where gaseous butyl cations from ...
Related Articles:
Synthesis of new sterically hindered anilines
[Steele, Barry R.; Screttas, Constantinos G. Journal of the American Chemical Society, 2000 , vol. 122, # 10 p. 2391 - 2392]
[Rummel; Yunusov; Kalyuzhnaya; Shur Journal of Organometallic Chemistry, 2009 , vol. 694, # 9-10 p. 1467 - 1472]
Microwave-assisted silica-supported aluminum chloride-catalyzed Friedel-Crafts alkylation
[Zupp, Laurine R.; Campanella, Veronica L.; Rudzinski, Diandra M.; Beland, Franois; Priefer, Ronny Tetrahedron Letters, 2012 , vol. 53, # 39 p. 5343 - 5346]
[Rummel; Yunusov; Kalyuzhnaya; Shur Journal of Organometallic Chemistry, 2009 , vol. 694, # 9-10 p. 1467 - 1472]
[Rummel; Yunusov; Kalyuzhnaya; Shur Journal of Organometallic Chemistry, 2009 , vol. 694, # 9-10 p. 1467 - 1472]