An effect of application of chiral aluminium alkoxides and amides as adducts to zirconium catalyzed carbo-and cycloalumination of olefins

…, LV Parfenova, SV Pechatkina, AG Ibragimov…

Index: Khalilov, Leonard M.; Parfenova, Ludmila V.; Pechatkina, Svetlana V.; Ibragimov, Askhat G.; Genet, Jean P.; Dzhemilev, Usein M.; Beletskaya, Irina P. Journal of Organometallic Chemistry, 2004 , vol. 689, # 2 p. 444 - 453

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Citation Number: 8

Abstract

This paper is dedicated to a study of properties of the following novel optically active organoaluminium compounds (OACs):(1S, 2S)-l, 7, 7-trimethyl-2-[(dialkylalumina) oxy]- bicyclo [2.2. 1] heptanes and (1S)-N-(dialkylalumina)-6, 7-dimethoxy-1-methyl-1, 2, 3, 4- tetrahydroisoquinolines. The synthesis of the chiral OACs was carried out in the reaction of either natural camphor or salsolidine with both AlEt3 and i-Bu2AlH. The main goal of the ...