Protolyses of (CH 3) 3 SnM (CH 3) 3 (M= Sn, Ge, Si, C)

MJ Cuthbertson, DW Hawker, PR Wells

Index: Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R. Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24

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Citation Number: 3

Abstract

Abstract Product and kinetic studies on the reactions of hydrogen chloride in methanol solution with the substrates (CH 3) 3 SnM (CH 3) 3 (M= Sn; Ge and Si) show that both Sn M and Sn CH 3 cleavage reactions occur, at similar rates, and are followed by other reactions giving complex but explicable mixtures of products. Similar behaviour is observed for trifluoroacetolysis in carbon tetrachloride solution, and some intermediates are ...