Palladium-catalyzed silastannation of secondary propargylic alcohols and their derivatives

TE Nielsen, S Le Quement, D Tanner

Index: Synthesis, , # 9 p. 1381 - 1390

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Citation Number: 20

Abstract

... The reaction products are valuable intermediates in the synthesis of tri- and tetrasubstituted alkenes, eg via subsequent metal-catalyzed ... to the α-position of the alkoxy group using Ito's catalyst [Pd(OAc) 2 /tert-alkyl isocyanide], [9] or to the β-position via Pd(Ph 3 P) 4 catalysis. ...