The Journal of Organic Chemistry

Free-radical additions involving fluorine compounds. VII. 1 The addition of perhaloalkanes to vinyl ethyl ether and vinyl 2, 2, 2-trifluoroethyl ether

P Tarrant, EC Stump Jr

Index: Tarrant,P.; Stump,E.C. Journal of Organic Chemistry, 1964 , vol. 29, p. 1198 - 1202

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Citation Number: 29

Abstract

As part of a program designed to prepare new fluorine-containing monomers, the synthesis of some unsaturated fluoro ethers has been investigated. Earlier work'had shown that free- radioal addition of perhaloalkanes such as bromotrichloromethane, dibromodifluoromethane, and 1, 2-dibromo-2-chloro-1, 1, 2-trifluoroethane to allyl ethers could be accomplished easily to give adducts capable of transformation to both olefinic ...