Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2 (OH) 4]

…, LN Cavalcanti, C García-García

Index: Molander, Gary A.; Cavalcanti, Livia N.; Garcia-Garcia, Carolina Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6427 - 6439

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Citation Number: 47

Abstract

Arylboronic acids are gaining increased importance as reagents and target structures in a variety of useful applications. Recently, the palladium-catalyzed synthesis of arylboronic acids employing the atom-economical tetrahydroxydiboron (BBA) reagent has been reported. The high cost associated with palladium, combined with several limitations of both palladium-and copper-catalyzed processes, prompted us to develop an alternative ...

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