A Highly Stereoselective and Flexible Strategy for the Convergent Synthesis of Long??Chain Polydeoxypropionates: Application towards the Synthesis of the Glycolipid …

…, MA Müller, A Pfaltz, C Schneider

Index: Weise, Christian F.; Pischl, Matthias C.; Pfaltz, Andreas; Schneider, Christoph Journal of Organic Chemistry, 2012 , vol. 77, # 3 p. 1477 - 1488

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Abstract

Abstract A highly stereocontrolled and flexible access to biologically relevant polydeoxypropionates in optically pure form has been developed. Taking advantage of our previously established strategy for the asymmetric and stereodivergent synthesis of trideoxypropionate building blocks, we have now been able to assemble large polydeoxypropionate chains with defined configuration in a highly convergent manner. ...

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