Catalytic aerobic oxidative decarboxylation of α-hydroxy-acids. Methyl mandelate as a benzoyl anion equivalent
…, I Fernández, P Formentin, JR Pedro, AL Roselló…
Index: Blay, Gonzalo; Fernandez, Isabel; Formentin, Pilar; Pedro, Jose R.; Rosello, Antonio L.; Ruiz, Rafael; Journaux, Yves Tetrahedron Letters, 1998 , vol. 39, # 20 p. 3327 - 3330
Full Text: HTML
Citation Number: 21
Abstract
The monomeric square-planar cobalt (III) complex of bis-N, N′-disubstituted oxamides catalyses the oxidative decarboxylation of α-hydroxy acids with molecular oxygen/pivalaldehyde with very good yields. This reaction offers an interesting alternative in the use of methyl mandelate as a convenient benzoyl anion equivalent.
Related Articles:
[Adlerova,E. et al. Collection of Czechoslovak Chemical Communications, 1964 , vol. 29, p. 97 - 120]
[Adlerova,E. et al. Collection of Czechoslovak Chemical Communications, 1964 , vol. 29, p. 97 - 120]
[El-Gindy, Alaa Farmaco, 2005 , vol. 60, # 8 p. 689 - 699]
Hydrolytic profile for ester-or amide-linkage by carboxylesterases pI 5.3 and 4.5 from human liver.
[Takai, Satomi; Matsuda, Ayuka; Usami, Yoshiko; Adachi, Tetsuo; Sugiyama, Tadashi; Katagiri, Yoshihiro; Tatematsu, Masae; Hirano, Kazuyuki Biological and Pharmaceutical Bulletin, 1997 , vol. 20, # 8 p. 869 - 873]