Reaction of bis (trimethylsiloxy) phosphine with trimethylsilane

…, AE Pestunovich, AI Albanov, VA Kukhareva

Index: Voronkov; Pestunovich; Albanov; Kukhareva Russian Journal of General Chemistry, 2009 , vol. 79, # 6 p. 1080 - 1082

Full Text: HTML

Citation Number: 0

Abstract

Abstract Bis (trimethylsilyl)[3-(trimethylsilyl) propyl] phosphonate and trimethylsilyl [3- (trimethylsilyl) propyl]-phosphinate are obtained by the reaction of bis (trimethylsiloxy) phosphine with trimethylallylsilane and converted into [3-(trimethylsilyl) propyl] phosphinic and [3-(trimethylsilyl) propyl] phosphonic acid, respectively, by the reaction with methanol.

Related Articles:

Radical additions of bis (trimethylsilyl) phosphite to vinyltimethylsilane and vinyltriethoxysilane: Crystal structure of 2-trimethylsilylethane-phosphonic acid

[Mahmoudkhani, Amir H.; Langer, Vratislav; Lindqvist, Oliver Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 10 p. 2159 - 2168]

Silyl phosphites. 15. Reactions of silyl phosphites with. alpha.-halo carbonyl compounds. Elucidation of the mechanism of the Perkow reaction and related reactions …

[Sekine, Mitsuo; Okimoto, Kiyomi; Yamada, Khoji; Hata, Tsujiaki Journal of Organic Chemistry, 1981 , vol. 46, # 10 p. 2097 - 2107]

B (C 6 F 5) 3-catalyzed silylation versus reduction of phosphonic and phosphinic esters with hydrosilanes

[Denis, Jean-Marc; Forintos, Henrietta; Szelke, Helga; Keglevich, Gyoergy Tetrahedron Letters, 2002 , vol. 43, # 32 p. 5569 - 5571]

Diastereoselective addition of Di??(trimethylsilyl) phosphite to chiral N??(R)?螃窿?methylbenzyl and N??(1??methoxycarbonyl??iso??pentyl) Schiff bases of various aldehydes

[Lewkowski, Jaroslaw; Karpowicz, Rafal Heteroatom Chemistry, 2010 , vol. 21, # 5 p. 326 - 331]

An efficient method for the preparation of silyl esters of diphosphoric, phosphoric, and phosphorous acid

[Wessjohann, Ludger A.; Dessoy, Marco A. Polyhedron, 2014 , vol. 70, p. 133 - 137]

More Articles...