Synthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitriles
S Demir, M Yiğit, İ Özdemir
Index: Demir, Serpil; Yigit, Murat; Oezdemir, Ismail Journal of Organometallic Chemistry, 2013 , vol. 732, p. 21 - 26
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Citation Number: 2
Abstract
Benzimidazolium salts and their new rhodium complexes ([Rh (COD)(NHC) Cl]) were synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, and IR spectroscopy. The addition of arylboron to benzonitriles in the presence of a catalytic amount of rhodium NHC complexes was examined. Corresponding carbonyl compounds were obtained in good yields. This method allows for the preparation of a wide variety of ...
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