Hydroformylation of nitrogen-containing cyclic olefins via “in-situ” rhodium-phosphine catalysts
K Prókai-Tátrai, S Tőrös, B Heil
Index: Prokai-Tatrai, K.; Toeroes, S.; Heil, B. Journal of Organometallic Chemistry, 1986 , vol. 315, p. 231 - 236
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Citation Number: 11
Abstract
Abstract Hydroformylation of nitrogen-containing cyclic olefins (N-substituted nortropidines, N-methyl-1, 2, 3, 6-tetrahydropyridine (THP) with rhodium-PR 3 catalysts prepared “in situ” is reported. The nortropidines reacted rapidly when either trialkyl-or triaryl-type phosphines were used, and the regioselectivities were not significantly influenced by the nature of the phosphine. With the less basic THP the rates and selectivities were generally lower, and ...
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