Multi-purpose functionality for the structural elaboration of the piperazine-2, 5-dione motif
CLL Chai, JA Elix, PB Huleatt
Index: Chai, Christina L. L.; Elix, John A.; Huleatt, Paul B. Tetrahedron Letters, 2003 , vol. 44, # 2 p. 263 - 265
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Citation Number: 8
Abstract
Mild methods for controlled C-and N-alkylation of 3-benzyloxycarbonylpiperazine-2, 5- diones are reported. The benzyloxylcarbonyl substituent can also serve as latent functionality for N-acyliminium ion formation and subsequent trapping enables installation of new carbon and/or heteroatom substituents.
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