Preparation of substituted acetoxy silanes

HA Schuyten, JW Weaver, JD Reid

Index: Schuyten; Weaver; Reid Journal of the American Chemical Society, 1947 , vol. 69, p. 2111

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Citation Number: 32

Abstract

Summary 1. Hydrogen-halogen exchange reactions of triethylsilane with three aliphatic chlorides in the presence of aluminum chloride are reported. 2. n-Hexyl chloride gave n- hexane; neopentyl chloride and neopentylcarbinyl chloride gave the rearrangement products, isopentane and 2, 3-dimethylbutane, respectively. A mechanism for exchange of silicon-hydrogen with carbon-chlorine in the presence of aluminum chloride is proposed. ...