Intramolecular hydrosilation of. alpha.-hydroxy enol ethers: a new highly stereoselective route to polyhydroxylated molecules

…, Y Nakagawa, H Arai, N Higuchi, Y Ito

Index: Tamao, Kohei; Nakagawa, Yoshiki; Arai, Hitoshi; Higuchi, Noriko; Ito, Yoshihiko Journal of the American Chemical Society, 1988 ,  vol. 110, p. 3712 - 3714

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Citation Number: 80

Abstract

Stereoselective chemical synthesis of carbohydrates constitutes a large and challenging field in modern synthetic organic chemistry. 2 Among a wide variety of methodologies for stereoselective construction of polyoxygenated skeleton^,^ that being the most straightforward is the stereoselective introduction of two oxygen functionalities to the carbon- xirbon double bonds (Scheme I, route a), as represented by the Sharpless epoxidation4 or ...