Facile Synthesis of Hyper??Branched Tetraphosphanes and Tetraphosphane Chalcogenides

…, VA Kuimov, AI Albanov, NK Gusarova

Index: Trofimov, Boris A.; Malysheva, Svetlana F.; Belogorlova, Nataliya A.; Kuimov, Vladimir A.; Albanov, Alexander I.; Gusarova, Nina K. European Journal of Organic Chemistry, 2009 , # 20 p. 3427 - 3431

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Citation Number: 11

Abstract

Abstract Novel families of hyper-branched tertiary tetraphosphanes, tetraphosphane sulfides, and tetraphosphane selenides were synthesized in 72–97% yield by treating secondary phosphanes, phosphane sulfides, and phosphane selenides with the tetravinyl ether of pentaerythritol (UV irradiation, room temp. or AIBN, 65 C).(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)