Structural effects of the Grunwald–Winstein correlations in the solvolysis of some simple tertiary alkyl chlorides

…, Y Ohga, T Ushino, M Takasuka

Index: Takeuchi, Ken'ichi; Ohga, Yasushi; Ushino, Takuhiro; Takasuka, Masaaki Journal of Physical Organic Chemistry, 1997 , vol. 10, # 10 p. 717 - 724

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Citation Number: 27

Abstract

Abstract The rates of solvolysis in various solvents at 25 C were determined for five tertiary alkyl chlorides: 2-chloro-2, 4, 4-trimethylpentane (4), 2-chloro-2, 4-dimethylpentane, 2-chloro- 2-methylpentane, 1-chloro-1, 3, 3-trimethylcyclopentane (7) and 1-chloro-1- methylcyclopentane. The rate data were analysed on the basis of the original and extended Grunwald–Winstein-type equation [log (k/k 0)= mY Cl+ c and log (k/k 0)= lN T+ mY Cl+ c] ...