Journal of Organometallic Chemistry

Boron nitrogen compounds XLIII. The interaction of hydrazine-1, 2-bis (diphenylborane) with aldehydes, ketones and nitriles

TT Wang, K Niedenzu

Index: Wang, T. T.; Niedenzu, K. Journal of Organometallic Chemistry, 1972 , vol. 35, p. 231 - 235

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Abstract

Abstract The reaction of hydrazine-1, 2-bis (diphenylborane) with nitriles yields azines of borylamino ketones,(C 6 H 5) 2 B NH CR N N CR NH B (C 6 H 5) 2, which probably exist as coordinated bicyclic species. The interaction of the cited hydrazineborane with aldehydes and ketones appears to follow the same reaction path; however, due to the great affinity between boron and oxygen, derivatives of a C 6 H 5 BO species and azines ...