Gallium Hydride Complexes Stabilised by Multidentate Alkoxide Ligands: Precursors to Thin Films of Ga2O3 at Low Temperatures

…, LG Bloor, IP Parkin, CJ Carmalt

Index: Pugh, David; Bloor, Leanne G.; Parkin, Ivan P.; Carmalt, Claire J. Chemistry - A European Journal, 2012 , vol. 18, # 19 p. 6079 - 6087

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Citation Number: 14

Abstract

Abstract The donor-functionalised alkoxides {Me 3− x N (CH 2 CH 2 O) x}(L x; x= 1, 2) have been used to form gallium hydride complexes [{GaH 2 (L 1)} 2] and [{GaH (L 2)} 2] that are stable and isolable at room temperature. Along with a heteroleptic gallium tris (alkoxide) complex [Ga (L 1) 3] and the dimeric complex [{GaMe (L 2)} 2], these compounds have been used as single-source precursors for the deposition of Ga 2 O 3 by aerosol-assisted ...