A new facile synthesis of α-dicarbonyl compounds by oxidation of alkynes with Mo (VI) peroxocomplex promoted by mercuric acetate
FP Ballistreri, S Failla, GA Tomaselli, R Curci
Index: Ballistreri, Francesco P.; Failla, Salvatore; Tomaselli, Gaetano A.; Curci, Ruggero Tetrahedron Letters, 1986 , vol. 27, # 42 p. 5139 - 5142
Full Text: HTML
Citation Number: 26
Abstract
Abstract Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkyl alkynes with (HMPA) MoO (O 2) 2 in 1, 2-dichloroethane affords the corresponding α-diketones in good yields. Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system.
Related Articles:
Phase-transfer catalytic oxidation of terminal alkynes to keto aldehydes by dilute hydrogen peroxide
[Ballistreri, Francesco Paolo; Failla, Salvatore; Tomaselli, Gaetano Andrea Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 830 - 831]
Phase-transfer catalytic oxidation of terminal alkynes to keto aldehydes by dilute hydrogen peroxide
[Ballistreri, Francesco Paolo; Failla, Salvatore; Tomaselli, Gaetano Andrea Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 830 - 831]
Catalytic asymmetric allylation of aldehydes using the chiral (salen) chromium (III) complexes
[Kwiatkowski, Piotr; Chaladaj, Wojciech; Jurczak, Janusz Tetrahedron, 2006 , vol. 62, # 21 p. 5116 - 5125]
Preparation of 1, 1-Dialkoxy-2-alkanones
[Verhe, R.; Courtheyn, D.; Kimpe, N. De; Buyck, L. De; Schamp, N. Synthesis, 1982 , # 8 p. 667 - 670]