Quaternary ammonium enolates as synthetic intermediates. Trimethylsilylacetate: a new class of silylating reagent for ketones and alcohols

E Nakamura, T Murofushi, M Shimizu…

Index: Nakamura,E. et al. Journal of the American Chemical Society, 1976 , vol. 98, p. 2346 - 2348

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Citation Number: 100

Abstract

concentration in moles per liter. proximate line width is in parts per million at 13.5 MHz. for nonequivalent doubly bridging oxygens in 7 and 8 to be resolved. The quadruply bridging oxygen resonance for 8 was not observed due to lack of enrichment at this site. Examination of Figure 2 in its entirety confirms the correlation between upfield shift and increasing degree of bridging noted earlier. Moreover, the clustering of chemical shifts within the 0-Mo and O ...