Reaction of Alkene–Zirconocene Complexes and Cyclic Enol Ethers through New Reaction Pathways

J Barluenga, L Álvarez??Rodrigo…

Index: Barluenga, Jose; Alvarez-Rodrigo, Lucia; Rodriguez, Felix; Fananas, Francisco J. Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3932 - 3935

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Citation Number: 20

Abstract

4a Et 3a H2O H 5a 80 4a Et 3a D2O D 5b 81 4a Et 3a I2 I 5c 75 4a Et 3a CH2= CHCH2Cl [c] allyl 5d 82 4a Et 3a PhCH2Br [d] Bn 5e 68 4b Pent 3a H2O H 5 f 78 4b Pent 3a I2 I 5g 76 4c Me 3a I2 I 5h 70 4a Et 3b H2O H 5i 85 4a Et 3b D2O D 5j 81 4a Et 3b I2 I 5k 72 4b Pent 3b D2O D 5l 82 4b Pent 3b I2 I 5m 73 4c Me 3b I2 I 5n 78 4d H 3b H2O H 5o 82 4d H 3b I2 I 5p 70 [a] Pent= pentyl.[b] Based on starting enol ether 3.[c] CuCl (5 mol%) and LiCl (1 equiv) ...