Reactions of trifluoroamine oxide: a route to acyclic and cyclic fluoroamines and N-nitrosoamines

…, RL Kirchmeier, JM Shreeve

Index: Gupta, Om Dutt; Kirchmeier, Robert L.; Shreeve, Jean'ne M. Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2383 - 2386

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Citation Number: 17

Abstract

Abstract: Acyclic secondary fluoroamines and N-nitrosoamines R, NF and R 2 NN 0 (R= CH C, H5, nC H7. i-C3H7, nC, H9, i-C4H9, c-C6Hl I) and saturated nonaromatic heterocyclic fluoroamines and N-nitrosoamines R% F and R% NO [R= c-C4Hs, c-C5H, o, 2, 6-(CH3) 2-c- C5Hs, 2, 2, 6, 6-(CH,),-c-C5H6] were prepared by reacting trifluoroamine oxide (NF, O) with the respective amine at SO" C in a 1: 2 molar ratio. The amine hydrofluoride salts are also ...