Copper??Catalyzed Oxidative Transformation of Aryl Propargylic Azides to Aryl Propiolonitriles
T Wang, H Yin, N Jiao
Index: Wang, Teng; Yin, Hang; Jiao, Ning Advanced Synthesis and Catalysis, 2013 , vol. 355, # 6 p. 1207 - 1210
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Citation Number: 7
Abstract
Abstract A concise copper (I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.
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